Effective removal of crystal violet in the aqueous solution using magnetic composites originated from sugarcane bagasse

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Phuong Lan Tran-Nguyen, Kim-Phung Ly, Huynh-Giao Dang, Minh-Nhut Nguyen, Van-Phat Dang, Nguyen-Phuong-Dung Tran, Shella Permatasari Santoso, Maria Yuliana, Artik Elisa Angkawijaya, Tran Thi Bich Quyen, Tran Thi Minh Thu, Vo Hoang Khang

2025 Chemical Papers Vol. 79 Issue 4 Article Cited by 3 Quartile

Abstract

This study targeted to generating composites comprised of sugarcane bagasse (SCB) and magnetic particles (MPs) under a facile and low-cost approach. Moreover, the adsorption performance of composites, treated SCB, and MPs for crystal violet (CV) was evaluated. Cellulose fibers were firstly isolated from SCB with a two-step process and employed as a matrix material to randomly adhere MPs via an in situ chemical co-precipitation method at room temperature. The properties of the composite were determined through analysis methods such as X-ray diffractometer (XRD), scanning electron microscopy with energy-dispersive X-ray analysis (EDX/SEM), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), vibrating sample magnetometer (VSM), and Brunauer–Emmett–Teller (BET). Magnetization, surface area, and pore diameter of magnetic fiber composite were 11.1 emu/g, 20 m2/g, and 0.002 cm3/g, respectively. The characteristic peaks of cellulose and MPs were found in XRD results, whereas the Fe content in composite was 27.52%. FTIR spectra also exposed the characteristic functional groups of MPs and treated SCB. Additionally, the CV removal using composites was evaluated with the adsorption efficiency and capacity of 72.09% and 77.22 mg/g, respectively, at pH 7, an adsorbent dose of 2 g/L, a CV concentration of 150 mg/L within 30 min. The adsorption process corresponded to the Sips model and the pseudo-second-order kinetic model. Besides, the mechanism of CV adsorption was primarily characterized by heterogeneous adsorption on the surface and physical sorption. In short, the obtained composite was a promising adsorbent for treating the dye-containing wastewater. © The Author(s), under exclusive licence to the Institute of Chemistry, Slovak Academy of Sciences 2025.

Affiliations

Faculty of Mechanical Engineering, Can Tho University, Campus II, 3/2 Street, Can Tho City, 900100, Viet Nam; Faculty of Chemical Engineering, Can Tho University, Campus II, 3/2 Street, Can Tho City, 900100, Viet Nam; Stem Cell Laboratory, Department of Molecular Biology, Institute of Biotechnology and Food, Can Tho University, Campus II, 3/2 Street, Can Tho City, 900100, Viet Nam; Department of Materials Science and Engineering, National Taiwan University of Science and Technology, 43, Sec. 4, Keelung Rd., Taipei, 10607, Taiwan; Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan, 37, Surabaya, 60133, Indonesia; Center for Sustainable Resource Science, RIKEN, Yokohama, Japan; Faculty of Biotechnology, Chemical Engineering, Food Technology, Can Tho University of Technology, Can Tho City, Viet Nam; School of Basic Sciences, Tra Vinh University, Tra Vinh, Viet Nam