Response Surface-Optimized Isolation of Essential Fatty Acids via Castor Oil Dehydration

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Suratno Lourentius, Imanuel Anugerahwan, Brama Andika, Adriana Anteng Anggorowati, Ery Susiany Retnoningtyas, Kiky Corneliasari Sembiring, Wiyanti Fransisca Simanullang

2023 Journal of the Korean Chemical Society Vol. 67 Issue 1 Article Cited by 1 Quartile

Abstract

The reaction conditions optimization, including the temperature of the reaction, amount of catalyst required, and reaction time for the linoleic acids (LAs) and conjugated linoleic acids (CLAs) production by catalytic dehydration of castor oil via saponification was investigated by response surface methodology (RSM). It was confirmed that all three parameters (temperature, time, and amount of catalyst) were influential factors in isolating LAs and CLAs. When the temperature was increased, the iodine value increased, and the reaction time and catalyst amount increased. The optimal reaction conditions were: 240 ℃, 2.2 h reaction time, and 7 wt% catalyst amount. The maximum iodine value reached 156.25 with 91.69% conversion to the essential fatty acids. © 2023 Korean Chemical Society. All rights reserved.

Affiliations

Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Surabaya, 60112, Indonesia; Research Center for Chemistry, National Research and Innovation Agency, Jakarta, 10340, Indonesia